Science notes, chapter 7

Air

Textbook Science Form 1 (DLP), pages 194–218

By the end of this chapter you can

  • State the composition of air, explain why air is a mixture, give the uses of oxygen, nitrogen, carbon dioxide and inert gases, and describe how the carbon and oxygen cycles keep the gases in balance (7.1)
  • State the three conditions needed for combustion, relate them to how fire extinguishers work, and practise fire safety (7.2)
  • Define air pollution and air pollutants, name their sources and effects, and justify ways to prevent and control air pollution (7.3)

7.1Composition of Air

All living things need air to survive. Clean air has no colour and no smell, so we cannot see it, even though it contains many substances. You learned in Chapter 5 that air has mass and occupies space.

Air is a mixture of gases: nitrogen (78%), oxygen (21%), carbon dioxide (0.03%) and inert gases and other substances (0.97%). The inert gases are helium, neon, argon, krypton and xenon.
Pie chart: nitrogen 78%, oxygen 21%, inert gases and other substances 0.97%, carbon dioxide 0.03%
Composition of air. (Textbook Figure 7.1, p. 196)

Air also contains small amounts of water vapour, dust and microorganisms. Their amounts change with place and time. For example, there is more water vapour in a forest or after rain than on a hot, dry day. Some illnesses, such as fever, are caused by microorganisms carried in the air.

Remember the order from most to least: Nitrogen 78 → Oxygen 21 → Inert gases 0.97 → Carbon dioxide 0.03. The four numbers add up to 100.

Finding the percentage of oxygen in air (Activity 7.1)

Gas jar on a stand in a basin of water with a candle; gas jar divided into five equal parts
(a) Set-up before the candle is lit. (b) The gas jar is divided into five equal parts. (Textbook Figure 7.2, p. 197)
Gas jar over a lit candle; water level inside the jar rises
After the candle is lit. (Textbook Figure 7.3, p. 197)
  1. A lit candle is covered with the gas jar.
  2. The candle uses up the oxygen inside the jar as it burns.
  3. When the oxygen is used up, the flame goes out.
  4. Water rises into the jar to take the place of the oxygen used up.
  5. The water rises by about one fifth of the jar, so air contains about 20% oxygen.
Worked example
A gas jar holds 500 cm3 of air. After the candle goes out, 400 cm3 of gas is left.
Oxygen used = 500 − 400 = 100 cm3.   Percentage of oxygen = 100 ÷ 500 × 100 = 20%.

Is air a mixture or a compound?

Air is a mixture because its gases can be separated by a physical method — fractional distillation. (Fractional distillation separates a liquid mixture into parts with different boiling points, by boiling and condensing.)
Saying air is a compound. The gases in air are not chemically joined, and each gas keeps its own properties. That is why air is a mixture.

The importance of gases

GasUses
OxygenRespiration; burning fuel in rocket engines at high altitudes; welding and cutting steel; making many compounds
Carbon dioxidePhotosynthesis; making fizzy (carbonated) drinks; fire extinguishers; part of the carbon cycle
NitrogenMaking nitric acid and ammonia (for nitrogen fertilisers); part of the nitrogen cycle; liquid nitrogen as a cooling agent
Inert gasesHelium fills hot-air balloons and weather balloons; neon is used in advertising lights; argon fills light bulbs

Uses of gases: textbook Figure 7.5, p. 199.

Which gas would you use to fill a weather balloon, and which gas fills an ordinary light bulb?
Show answerHide answer
Helium fills weather balloons. Argon fills light bulbs. Both are inert gases.

The carbon cycle

Carbon cycle: animals, plants, decomposition and burning fossil fuels release carbon dioxide; photosynthesis uses it
Red arrows release carbon dioxide; blue arrows use it. (Textbook Figure 7.6, p. 200)
The carbon cycle keeps the amount of carbon dioxide in the air steady by continuously taking carbon dioxide from the air and returning it to the air.
  • Green plants take in carbon dioxide during photosynthesis.
  • Animals get carbon by eating plants.
  • Plants and animals release carbon dioxide during respiration.
  • When they die, bacteria and fungi decompose them and release carbon dioxide.
  • Dead organisms buried for a very long time form fossil fuels (petroleum, natural gas, coal). Burning fossil fuels releases carbon dioxide.
  • Respiration, decomposition and combustion (release) are balanced by photosynthesis (use).

The oxygen cycle

Oxygen cycle: respiration, combustion, rusting and decomposition use oxygen; photosynthesis releases oxygen
Respiration, combustion, rusting and decomposition use oxygen; photosynthesis releases it. (Textbook Figure 7.7, p. 201)
The oxygen cycle is a continuous cycle that takes oxygen from the air and returns it to the air. The oxygen used in respiration, combustion, rusting and decomposition is replaced by photosynthesis.
Photosynthesis is the only process in both cycles that uses carbon dioxide and releases oxygen. Every other process uses oxygen and releases carbon dioxide (rusting only uses oxygen).

Interference to the cycles and how to prevent it

Human activities such as logging (cutting down trees), open burning and too much use of pesticides upset the cycles. Fewer plants means less carbon dioxide is taken in, so carbon dioxide builds up in the air. This leads to the greenhouse effect and global warming, and fertile land can become dry.

Do notDo
Log illegallyReforestation — plant trees again
Burn forestsPrevent too much smoke from vehicles
Use too many pesticidesReduce activities that harm the air

Ways to reduce interference: textbook Photograph 7.4, p. 203.

Explain why cutting down a large forest increases the carbon dioxide in the air.
Show answerHide answer
Trees take in carbon dioxide for photosynthesis. With fewer trees, less carbon dioxide is removed, while respiration, decomposition and burning keep releasing it — so the amount in the air goes up.

7.2Combustion

Combustion is the reaction that happens when a substance is heated in the presence of oxygen, producing heat energy and light energy.
Fire triangle with sides oxygen, fuel and heat
The three conditions needed for combustion. (Textbook Figure 7.8, p. 204)

Combustion needs all three conditions:

  • Fuel — something that can burn (wood, candle wax, paper, petrol)
  • Oxygen — from the air
  • Heat — enough to make the fuel start burning

Remove any one and the fire goes out. Blowing out a birthday candle works this way.

Proving the three conditions (Activity 7.3)

ConditionWhat is doneResult and conclusion
FuelHold a glass rod, wood, a candle and a stone in a Bunsen flameWood and candle burn (fuels); glass rod and stone do not (non-fuels). Fuel is needed.
OxygenCover candle X with a gas jar; leave candle Y uncoveredCandle X goes out first because its oxygen is used up; Y keeps getting oxygen from the air. Oxygen is needed.
HeatStrike match P (kept in a refrigerator) and match Q (room temperature)The cold match P is harder to light. Heat is needed.
Candle X covered by a gas jar and candle Y uncovered, both on white tiles
Candle X is covered by a gas jar; candle Y is not. (Textbook Figure 7.9, p. 205)

Fire extinguishers

A fire extinguisher is a safety tool for putting out a small fire, usually in an emergency. The substance inside depends on what is burning.

Material on fireExamplesSuitable extinguisher
SolidWood, cloth, paperWater, dry powder
LiquidOil, varnish, paintFoam, dry powder, carbon dioxide
GasPropane, acetylene, methaneFoam, dry powder, carbon dioxide
MetalPotassium, sodium, magnesium, calciumDry powder, dry sand

Table 7.1, textbook p. 206.

Cartoon: a pot of oil on fire; a woman says pour water, a man uses a foam extinguisher
Never pour water on burning oil. (Textbook "Science in Life", p. 206)
Putting out an oil fire with water. Water is denser than oil, so it sinks below the oil and the oil keeps burning (it can even splash and spread the fire). Use foam to cover it.

How fires are put out

Each method removes one of the three conditions:

MethodWhat it doesCondition removed
CoveringCuts off the fuel from air — fire blanket, wet sack, sand, soil, mud or foamOxygen
CoolingSprays water or carbon dioxide onto the burning materialHeat
Removing fuelSeparates burning materials, moves unburnt materials away, shuts off the gas or oil supplyFuel
A fire blanket is made of fire-resistant material. It covers the fire and stops oxygen from reaching it, so the fire goes out.

Preventing fires

Six safety measures to prevent fire
Safety measures to prevent fire. (Textbook Figure 7.11, p. 207)
  • Keep flammable substances away from fire; keep matches and lighters in a safe place.
  • Always be aware of the electrical appliances you are using; do not plug too many appliances into one socket.
  • Do not throw away cigarette butts that are still burning.
  • Install a fire alarm and smoke detector at home.
Why are metals such as potassium and sodium kept in paraffin oil?
Show answerHide answer
They catch fire / react when exposed to air. The paraffin oil keeps air (oxygen) away from them.

7.3Air Pollution

Air pollution is the presence of pollutants in the air that bring harm and discomfort to living things and destroy the environment. Air pollutants are the harmful substances that cause it.

Sources of air pollutants

Globe showing sources of air pollutants and the pollutants they release
Sources of air pollutants. (Textbook Figure 7.12, p. 209)
SourcesPollutants
Vehicle exhaust, factoriesSmoke, soot, dust, carbon monoxide, sulphur dioxide, nitrogen dioxide, lead (plumbum)
Open burning, cigarettes, forest firesDust, soot, smoke
Construction sites, asbestos factories, limestone quarriesDust, soot
Nuclear power plantsRadioactive materials
Agriculture and plantationsAerosol spray, chemical fertilisers
Air-conditioners, refrigerators, aerosol sprays, electronic factoriesChlorofluorocarbons (CFC)

The Air Pollutant Index (API)

Haze from open burning has affected Malaysia for many years. The Air Pollutant Index (API) tells us how polluted the air is and how it may affect our health.

APILevel of pollution
0 – 50Good
51 – 100Moderate
101 – 200Unhealthy
201 – 300Very unhealthy
Above 300Hazardous

Table 1, textbook p. 195.

Effects of air pollution

AffectsEffects
HealthSmoke and dust cause breathing problems; sulphur dioxide causes respiratory problems; carbon monoxide causes headaches, mental retardation and death; asbestos particles cause lung cancer; lead particles cause intellectual disability in children and babies
BuildingsDust and soot stain buildings; acid rain corrodes concrete and limestone and speeds up rusting of iron
Plants and animalsAcid rain makes soil acidic and less fertile, and makes water unsuitable for aquatic life; smoke and haze block sunlight and lower the rate of photosynthesis
ClimateSmoke causes haze; too much carbon dioxide adds to the greenhouse effect; CFCs thin the ozone layer; sulphur dioxide and nitrogen dioxide cause acid rain

Figure 7.13 (a), textbook p. 210.

Link each pollutant to its main effect: carbon dioxide → greenhouse effect; sulphur dioxide / nitrogen dioxide → acid rain; CFC → thinning of the ozone layer; carbon monoxide → headache, death.
Mixing up carbon dioxide and carbon monoxide. Carbon dioxide (CO2) causes the greenhouse effect. Carbon monoxide (CO), from vehicle exhaust, is poisonous to people.

Preventing and controlling air pollution

ApproachExamples
Law enforcementFine people who smoke in restricted areas, carry out open burning, or drive vehicles with too much smoke; do not allow factories in housing areas
EducationTeach the effects of air pollution; anti-smoking campaigns; encourage walking, cycling, public transport and car pooling
Science and technologyHybrid vehicles; catalytic converters on vehicles; filters in factory chimneys; refrigerators using HCFC instead of CFC; biological control instead of pesticides

Figure 7.13 (b), textbook p. 211.

Explain how littering can cause air pollution.
Show answerHide answer
Rotting rubbish increases the microorganisms in the air (and burning rubbish releases smoke).

Summary

RememberKey fact
Composition of airNitrogen 78%, oxygen 21%, inert gases and others 0.97%, carbon dioxide 0.03%
Air is a mixtureIts gases are separated by a physical method (fractional distillation)
Inert gas usesHelium — balloons; neon — advertising lights; argon — light bulbs
Carbon and oxygen cyclesPhotosynthesis uses CO2 and releases O2; respiration, combustion, decomposition (and rusting) use O2
CombustionNeeds fuel, oxygen and heat; produces heat and light
Putting out fireCovering (oxygen), cooling (heat), removing fuel (fuel); oil fire → foam; metal fire → dry powder / dry sand
Air pollutionPollutants in the air harm living things; CO2 → greenhouse effect, SO2/NO2 → acid rain, CFC → ozone thinning
API0–50 good, 51–100 moderate, 101–200 unhealthy, 201–300 very unhealthy, above 300 hazardous