Chemistry questions, chapter 5
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Chemical Bond
45 marks. Use Practice to check each answer as you go, or Exam to answer everything against the clock first.
Section A: objective questions
13 marksChoose the best answer for each question.
1
Question 1
Why are noble gases unreactive and unable to form compounds?
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B
Noble gases already have a stable duplet (helium) or octet electron arrangement, so they do not need to transfer or share electrons.
2
Question 2
Which half-equation shows the formation of the fluoride ion?
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A
A fluorine atom (2.7) accepts one electron to become F− (2.8).
3
Question 3
Element P has proton number 12 and element Q has proton number 17. What is the formula of the compound they form?
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C
P is 2.8.2 and donates 2 electrons (P2+). Q is 2.8.7 and accepts 1 electron (Q−). Two Q ions balance one P ion, so PQ2.
4
Question 4
How many pairs of electrons are shared between the atoms in a nitrogen molecule, N2?
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D
Nitrogen (2.5) needs 3 more electrons, so two atoms share 3 pairs, forming a triple bond.
5
Question 5
Which molecule contains a double bond?
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B
Oxygen (2.6) shares two pairs of electrons. H2 and Cl2 have single bonds and N2 has a triple bond.
6
Question 6
An atom of element Y has the electron arrangement 2.5. How many hydrogen atoms bond with one atom of Y in a covalent compound?
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C
Y has 5 valence electrons and needs 3 more for an octet, so it shares with 3 hydrogen atoms (like NH3).
7
Question 7
Which compound can form hydrogen bonds between its molecules?
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A
Hydrogen bonds form when H is bonded to N, O or F. In H2O, hydrogen is bonded to oxygen. Cl, and C in CH4, do not qualify.
8
Question 8
Ethanol, C2H5OH, dissolves in water. What is the reason?
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D
The O–H group in ethanol forms hydrogen bonds with water molecules, so it dissolves.
9
Question 9
Which ion contains a dative bond?
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C
In NH4+ the nitrogen lone pair in NH3 is shared with H+, a dative bond. The other ions are simple monoatomic ions.
10
Question 10
Why can a metal conduct electricity?
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B
Valence electrons are delocalised in a sea of electrons and move from the negative to the positive terminal.
11
Question 11
Table 1 shows the properties of four substances. Which substance is a giant covalent compound?
| Substance | Melting point (°C) | Soluble in water | Conducts electricity (solid and molten) |
|---|---|---|---|
| P | 801 | Yes | Only when molten |
| Q | −7 | No | No |
| R | 1 710 | No | No |
| S | 1 085 | No | Yes |
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D
R has a very high melting point, does not dissolve and does not conduct: giant covalent. P is ionic, Q is a simple molecule and S is a metal.
12
Question 12
Why does sodium chloride dissolve in water?
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C
Water is a polar solvent. Its partial charges attract Na+ and Cl− and break up the lattice.
13
Question 13
A student says: "Solid sodium chloride contains ions, so it should conduct electricity." Which statement evaluates this best?
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D
Ions must be free to move to carry charge. In the solid they are fixed in the lattice; they move only when molten or dissolved.
Section B: structured questions
32 marksAnswer all questions. Write your answers in the spaces provided.
14
Question 14
Atom P has proton number 11 and atom Q has proton number 17. They react to form compound PQ.
[2 marks]
(a)Write the electron arrangement of atom P and atom Q.
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[2 marks]
(b)Write the half-equation for the formation of each ion.
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[1 mark]
(c)State the type of bond in PQ.
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[2 marks]
(d)Explain how the bond in PQ is formed.
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15
Question 15
Methane, CH4, is formed from carbon (proton number 6) and hydrogen (proton number 1). You are asked to draw its Lewis structure.
[1 mark]
(a)State the number of valence electrons in a carbon atom and in a hydrogen atom.
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[2 marks]
(b)Describe the Lewis structure you would draw.
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16
Question 16
Diagram 1 shows the valence electrons in a molecule of element X (X is not the actual symbol).
[1 mark]
(a)How many pairs of electrons are shared?
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[1 mark]
(b)State the type of covalent bond.
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[1 mark]
(c)How many valence electrons does one atom of X have?
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[2 marks]
(d)X2 has a low melting point. Explain why.
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17
Question 17
Water, H2O, is a liquid at room temperature but hydrogen chloride, HCl, is a gas.
[1 mark]
(a)Name the attraction force that exists between water molecules besides Van der Waals forces.
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[3 marks]
(b)Explain why water is a liquid but HCl is a gas at room temperature.
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[1 mark]
(c)Give one effect of hydrogen bonds in daily life.
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18
Question 18
A dative bond is formed in the ammonium ion, NH4+. [Proton number: H = 1, N = 7]
[1 mark]
(a)What is a dative bond?
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[3 marks]
(b)Explain the formation of the dative bond in NH4+.
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[2 marks]
(c)Boron in BF3 has only six valence electrons. Can BF3 form a dative bond with NH3? Explain.
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19
Question 19
Table 2 shows the properties of compounds J and K.
| Compound | Melting point (°C) | Conducts when solid | Conducts when molten |
|---|---|---|---|
| J | 770 | No | Yes |
| K | 80 | No | No |
[2 marks]
(a)State the type of compound (ionic or covalent) for J and for K.
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[2 marks]
(b)Explain why J conducts electricity when molten but not when solid.
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[2 marks]
(c)Explain why J has a much higher melting point than K.
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